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Preparation of N-doped carbon-modified Na3V2(PO4)2F3 based on ZIF-8 as a template and its electrochemical properties

Journal 2024 · IF 4.3 · 发表于 2024 年 4 月 21 日
作者: Fenghai Zhou,Wei Li,Junjie Ma,Shaocong Wang,Mingjun Lu,Zheng Liu,Guo-Cheng Han
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摘要

N-doped porous carbon material (N-PC) was generated through high-temperature cracking, using ZIF-8 as a template, and preparation of Na 3 V 2 (PO 4 ) 2 F 3 /N-PC composites were designed and prepared as cathode materials for sodium-ion batteries, and the electrochemical sodium storage performance was systematically investigated. The physical characterization results showed that the addition of N-PC played a role in increasing the electrical conductivity of Na 3 V 2 (PO 4 ) 2 F 3 material and improving the specific surface area. The electrochemical test results showed that the discharge specific capacity of Na 3 V 2 (PO 4 ) 2 F 3 /N-PC composite was 109.56 mAh/g at 0.1C, and the capacity retention rate was 85.10 % after 100 cycles, and the R SEI of Na 3 V 2 (PO 4 ) 2 F 3 /N-PC composite (81.55 Ω) is better than that of Na 3 V 2 (PO 4 ) 2 F 3 pure-phase material (142.5 Ω), which indicates that the ion transfer impedance of the modified material has been effectively reduced, and the ion de-embedding is more fluent.

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