Preparation of phosphorylated rice husk for cadmium adsorption: Crucial role of phosphonyl group

Rice husk is a locally available biomass for preparation of adsorbents to deal with cadmium (Cd) contamination in paddy system. In this study, phosphorylation of rice husk using H 3 PO 4 and NH 4 H 2 PO 4 was carried out in the presence of urea at 165℃ to obtain APB-C and NPB-C, respectively. According to the material characterizations, phosphonyl groups were successfully grafted on the rice husk. Both APB-C and NPB-C had high performance for Cd(II) adsorption with the capacities of 146 and 129 mg/g, respectively. The main mechanism of Cd(II) adsorption was ion exchange with NH 4 + . The adsorption capacity was linearly corelated with phosphorus content (R 2  = 0.9997), while the Langmuir constant had high correlation efficient (R 2  = 0.996) with phosphonyl group percentage. Further quantum chemical calculation showed higher interaction energy between Cd(II) and phosphonyl group than other groups. These results indicated that phosphonyl group governed Cd(II) adsorption on phosphorylated biomass.