Surface Defects-Induced Photoactivation of Carbon Dots-NiFe2O4 Nanocomposite: Synthesis, Mechanism and Applications

The optical properties of quantum dots are significantly influenced by photoactivation. However, the progress in the development of photoactivation carbon dot (CDs) is still stagnant. Herein, a method for preparing photoactivated CDs/NiFe 2 O 4 by introducing affluent defects onto the surface of CDs through modification with NiFe 2 O 4 , extremely filling the gap of photoactivated CDs is proposed. Interestingly, a fantastic fluorescence detection strategy in a unique “OFF-ON-OFF” mode, combined with Ag + -assisted fluorescence enhancement, to establish a dual-channel regulation mechanism for ultra-sensitive detection of Hg 2+ is first proposed. By increasing surface traps and non-radiative recombination, defect-induced manipulation on the surface of CDs creates favorable conditions for enhancing photoactivation capacity. Unexpectedly, the CDs/NiFe 2 O 4 shows a 25-fold enhancement in fluorescence intensity after exposure to UV-lamp. Compared to CDs/NiFe 2 O 4 , Ag + -assisted photoactivation CDs/NiFe 2 O 4 exhibits superior selectivity and sensitivity for Hg 2+ detection, with low detection limits of 0.7 nM. Moreover, TiO 2 @CDs/NiFe 2 O 4 catalyst is successfully prepared by anchoring CDs/NiFe 2 O 4 onto the surface of TiO 2 , which demonstrates efficient degradation of tetracycline within 90 min under visible light irradiation, with a degradation rate of 98.3%. This work first provides a novel defects modification strategy for developing highly active photoactivated CDs technology that is significant for future environmentally sensitive applications.