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Hydrogenation of 3-methylcyclopentadecenone to synthesize muscone with Pd/N-doped graphene catalysts

Journal 2025 · IF 3.9 · 发表于 2025 年 9 月 11 日
作者: Gao Minjie,Yang Zongmei,Song Senchuan,Liu Xigui,Wang Fei
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摘要

A series of Pd/N-doped graphene catalysts were designed for the efficient and highly selective synthesis of muscone through the hydrogenation of 3-methylcyclopentadecenone (XT). The catalysts were characterized using FT-IR, BET, XPS, XRD, Raman and SEM–EDS. All results indicated the uniform dispersion of Pd on NG. By optimizing reaction conditions, the hydrogenation of XT achieved a high yield and selectivity of muscone, producing a 99% yield at 2 MPa H 2 and 90 °C in 10 h using a 10 wt% Pd/N-doped graphene catalyst functionalized with melamine (Pd/NmG), which significantly outperformed conventional Pd/C catalysts. Graphical abstract

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