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Construction of ultra-thin 2D CN-Br0.12/2%RhOx photo-catalyst with rapid electron and hole separation for efficient bisphenol A degradation

Journal 2021 · IF 19.503 · 发表于 2021 年 8 月 13 日
作者: Heng Fei,Junxia Shao,Hua Li,Najun Li,Dongyun Chen,Qingfeng Xu,Jinghui He,Jianmei Lu
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摘要

g-C 3 N 4 (CN), which shows enormous potential for photocatalysis, has long been studied, but still exhibits an unsatisfactory degradation rate. Herein, dual cocatalysts, Br and ultrafine RhO x nanoparticles, were constructed on ultrathin CN for synergetic photocatalysis. Ultrathin CN increased the exciton separation efficiency, while cocatalysts Br and RhO x can accelerated electron and hole transfer simultaneously, maximizing the photocatalytic degradation performance of CN. This CN-Br 0.12 /2%RhO x degraded 10 ppm bisphenol A (BPA) in 9 min, which represents the fastest degradation rate reported to date. This excellent performance was also demonstrated by a larger photocurrent response, higher separation efficiency, and faster transfer rate for electron–hole pairs than CN. This work obtained an enhanced electron–hole separation efficiency and migration rate by combing ultrathin CN with dual-channel cocatalysts, leading to the best photocatalytic degradation performance reported for CN.