Ultrahigh-Resolution Full-Color Quantum Dot LEDs Based on Region-Selective Interfacial Self-Assembly

Colloidal quantum dots (QDs) have shown great promise in the development of high-resolution displays for near-eye visual communication with the outside world. However, achieving full-color high-precision assembly of QDs at the nanoscale remains a critical challenge. This study proposes a novel strategy for the region-selective assembly of QDs for achieving ultra-high-resolution light-emitting devices. This approach leverages interface-assembled ultrathin surface microstructures to create specific wettability patterns, guiding the selective assembly of QDs on their surfaces. Ultimately, an ultra-high-resolution 36 599 pixels per inch (PPI) light-emitting device is successfully realized, with a record-high external quantum efficiency (EQE) of 18.74%. The addition of a molecular microstructure enhances the fidelity of the assembled QDs pattern, providing nearly a two-fold increase in contrast ratio while effectively suppressing device leakage current. Additionally, the assembly process is compatible with photo-crosslinking technology, resulting in a full-color light-emitting device with an EQE of 11.01%. Our strategy paves a simple and effective way for advancements in high-performance nano-display technology.