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A novel array of chemiluminescence sensors for sensitive, rapid and high-throughput detection of explosive triacetone triperoxide at the scene

Journal 2013 · IF 5.437 · 发表于 2013 年 3 月 21 日
作者: Xiaohua Li,Zhujun Zhang,Liang Tao
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摘要

Triacetone triperoxide (TATP) is relatively easy to make and has been used in various terrorist acts. Early but easy detection of TATP is highly desired. We designed a new type sensor array for H 2 O 2 . The unique CL sensor array was based on CeO 2 nanoparticles' membranes, which have an excellent catalytic effect on the luminol–H 2 O 2 CL reaction in alkaline medium . It exhibits a linear range for the detection of H 2 O 2 from 1.0×10 −8 to 5.0×10 −5   M ( R 2 =0.9991) with a 1   s response time. The detection limit is 1.0×10 −9   M. Notably, the present approach allows the design of CL sensor array assays in a more simple, time-saving, long-lifetime, high-throughput, and economical approach when compared with conventional CL sensor. It is conceptually different from conventional CL sensor assays. The novel sensor array has been successfully applied for the detection of TATP at the scene.

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