Constructing heterojunction-induced oxygen vacancies of N-doped carbon-encapsulated Sn/SnOx microplates for boosting lithium storage capability

Heterogeneous Sn/SnO x @N-doped carbon (Sn/SnO x @NC) microplates with oxygen vacancies evolved from plate-like SnO powders are successfully fabricated, in which SnO powders are converted into Sn, SnO 2 , and Sn 2 O 3 phases by rationally sintering and are perfectly in situ encapsulated by polyaniline-derived NC layer. By elaborately constructing the particular structure, high discharge specific capacity of 730.4 mAh/g and capacity retention ratio of 98.3 % after 110 cycles at 0.1 A/g are realized for optimal Sn/SnO x @NC composite electrode. Benefiting from enhanced electronic conductivity and Li + ions diffusion kinetics, the assembled cell delivers reversible discharge specific capacity of 487.3 mAh/g at 1.0 A/g after 500 cycles. First principles calculation and in / ex situ characterization reveal that in situ formed heterostructure with oxygen vacancies and NC layer synergistically improve interfacial charge transfer and reaction reversibility to promote lithium storage capability. Therefore, fabricating Sn/SnO x @NC microplates may provide a practical strategy to design heterogeneous and oxygen-deficient Sn-based anode materials for high-performance lithium-ion batteries.