Electrochemical detection of As(Ⅲ): Innovations with FeSx@MOF-808/Ti3C2Tx composite materials

Arsenic contamination in water poses significant health risks, necessitating effective detection methods to ensure public safety. In this study, a novel FeS x @MOF-808/Ti 3 C 2 T x composite sensor was introduced for the electrochemical detection of arsenite (As(III)), a highly toxic form of arsenic. Based on a straightforward synthetic approach, the composite enhances the sensitivity and selectivity for As(III) detection. The electrochemical performance in various buffer solutions was characterized through square wave anodic stripping voltammetry. The sensor demonstrated exceptional sensitivity with a detection limit of 0.02 ng/mL and a broad linear response range of 0.05–100 ng/mL, surpassing World Health Organization guidelines. Notably, the FeS x @MOF-808/Ti 3 C 2 T x composite exhibited minimal interference from common heavy metals. The superior adsorption properties, attributed to the high surface area and porosity of the composite, facilitated rapid arsenic ion capture. The developed FeS x @MOF-808/Ti 3 C 2 T x sensor offers a robust platform for reliable As(III) detection in diverse water matrices. This innovation contributes to environmental monitoring, providing a cost-effective and efficient method for arsenic detection, particularly in resource-limited regions. The findings underscore the potential of integrating advanced materials into electrochemical sensors, thereby paving the way for future developments in sustainable water quality management.