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Molten salts synthesized L-Ta2O5:Er3+/Yb3+ with superior pure green upconversion luminescence

Journal 2025 · IF 3.8 · 发表于 2025 年 4 月 16 日
作者: Yuhan Fan,Yongze Cao,Meiling Li,Guojian Li,Shang Sun,Yichao Wang,Xu Sai,Jinsu Zhang,Baojiu Chen
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摘要

L-Ta 2 O 5 :Er 3+ /Yb 3+ upconversion phosphors were synthesized by employing the molten salts method with B 2 O 3 as solvent. The optimal doping concentrations of Er 3+ and Yb 3+ are 0.2 and 2.5 mol%, respectively. The green upconversion luminescence (UCL) integral intensity of the acid-pickling sample reached 40% of β-NaYF 4 :Er 3+ /Yb 3+ under 980 nm laser excitation. Er 3+ /Yb 3+ may take the sites of Ta 5+ and insert into the interlayers of L-Ta 2 O 5 . Using the luminescence intensity ratio (LIR) technique, the relative temperature sensitivity was obtained to be 0.95 %K −1 at 303 K. L-Ta 2 O 5 :Er 3+ /Yb 3+ with outstanding pure green UCL intensity and high-temperature sensitivity can be applied to luminescence display and temperature sensing.

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