“All-in-One Functionalization and Synergic Ordering” Strategy Enables Multimode Anti-Counterfeiting Patterns

Conventional multimode anticounterfeiting systems usually suffer high cost, complicated structures, and different optical channel interferences. In this study, we demonstrate a simple strategy named “all-in-one functionalization and synergic ordering” to prepare quadruple mode patterns on a photoresponsive alternating copolymer P(DPA-alt-BP) film. Herein, a 9,10-diphenylanthracene (DPA) nonanoate unit serves as the multipurpose moiety with photoresponse and fluorescence, performing photodimerization upon 365 nm UV irradiation. The liquid crystal mesogen biphenyl (BP) caproate units can orderly align along strain for polarized sight and improve the microphase separation. Upon UV irradiation through a photomask followed by solvent annealing, the P(DPA-alt-BP) film is first gradient-cross-linked and then undergoes stress relief and microphase separation, giving rise to a synergic ordering effect that enables fabrication of an anticounterfeiting pattern with quadruple modes, i.e., wrinkled pattern, substructure on a wrinkled surface, distinguishable fluorescent emission, and polarized sight on the film. This strategy is promising for high-level anticounterfeiting applications and provides helpful inspiration to the development of innovative photoresponsive materials.