摘要
Thermally evaporated perovskite light-emitting diodes (PeLEDs) have emerged as a promising technology for next-generation display applications. However, achieving high luminance remains a critical challenge. In this study, a significant enhancement in the luminance of fully vacuum-evaporated PeLEDs is demonstrated by optimizing both the crystallinity of perovskite films and hole injection efficiency. A lateral 0D/3D Cs 4 PbBr 6 /MA x Cs 1-x PbBr 3 heterostructure is achieved via co-evaporation of MABr (MA + = CH 3 NH 3 + ), CsBr, and PbBr 2 . Theoretical calculations indicate that MAPbBr 3 , with its lower formation energy, preferentially forms and serves as a nucleation site for the growth of high-quality MA x Cs 1-x PbBr 3 , significantly improving crystallization. Excess CsBr and PbBr 2 react to form Cs 4 PbBr 6 , which passivates defects and confines excitons, thereby enhancing photoluminescence efficiency. The resulting perovskite films exhibit suppressed non-radiative recombination. Additionally, hole injection and transport efficiency are improved through p-type doping, ensuring sufficient carrier injection for high-luminance emission. As a result, the optimized PeLEDs achieve a maximum brightness of 246, 211 cd m − 2 , representing the highest level reported to date for thermally evaporated PeLEDs. These findings underscore the potential of thermally evaporated perovskites for high-brightness display and lighting applications.
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