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Volumetric and Viscometric Analysis of Aggregation Behavior in 2-(Methylamino)ethanol (MAE) + Dimethyl Sulfoxide (DMSO) Non-Aqueous Solutions

Journal 2025 · IF 3.5 · 发表于 2025 年 10 月 8 日
作者: Jian Ma,Yixiao Wang,Jichao Hu,Gaoqi Han,Lemeng Wang,Huiying Gao,Pan Zhang,Kangrui Li,Dong Fu
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摘要

This study determined and correlated the density and viscosity of the 2-(methylamino)ethanol (MAE) - dimethyl sulfoxide (DMSO) non-aqueous solution over a temperature range of 298.15 to 323.15 K at atmospheric pressure. The effects of the mass fraction of MAE ( w 1 ), temperature ( T ) and CO 2 loading ( α ) on viscosity and density were demonstrated based on of experimental data and calculations. The excess molar volume ( V m E ) and viscosity deviation ( Δη ) were derived from the experimental data. Furthermore, the V m E and Δη were correlated by using the Redlich-Kister equation. The viscosity activation energy and CO 2 diffusion coefficient were calculated and analyzed by utilizing viscosity data. The activation parameters activation enthalpy (Δ Η* ) and activation entropy (Δ S* ) were determined using the measured viscosity and density data. This combined study provides insights into intermolecular interactions and transportation characteristics through the observed changes in viscosity and density with composition.

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