Freestanding Transparent Organic–Inorganic Mesh E-Tattoo for Breathable Bioelectrical Membranes with Enhanced Capillary-Driven Adhesion

The electronic tattoo (e-tattoo), a cutting-edge wearable sensor technology adhered to human skin, has garnered significant attention for its potential in brain–computer interfaces (BCIs) and routine health monitoring. Conventionally, flexible substrates with adhesion force on dewy surfaces pursue seamless contact with skin, employing compact airtight substrates, hindering air circulation between skin and the surrounding environment, and compromising long-term wearing comfort. To address these challenges, we have developed a freestanding transparent e-tattoo featuring flexible serpentine mesh bridges with a unique full-breathable multilayer structure. The mesh e-tattoo demonstrates remarkable ductility and air permeability while maintaining robust electronic properties, even after significant mechanical deformation. Furthermore, it exhibits an impressive visible-light transmittance of up to 95%, coupled with a low sheet resistance of 0.268 Ω sq–1, ensuring both optical clarity and electrical efficiency. By increasing the number of menisci between the mesh e-tattoo and the skin, the total adhesion force increases due to the cumulative capillary-driven effect. We also successfully demonstrated high-quality bioelectric signal collections. In particular, the controlling virtual reality (VR) objects using electrooculogram (EOG) signals collected by mesh e-tattoos were achieved to demonstrate their potential for human–computer interactions (HCIs). This freestanding transparent e-tattoo with a fully breathable mesh structure represents a significant advancement in flexible electrodes for bioelectrical signal monitoring applications.