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Nacre-inspired NH2–BNNSs/epoxy lamellar coatings: Exceptional anti-corrosion performance via biomimetic layered architecture

Journal 2025 · IF 7.3 · 发表于 2025 年 11 月 4 日
作者: Yuanxia Wang,Xiangju Liu,Nazhen Liu,Chen Guo,Yongchao Dai,Ziang Su,Quantong Jiang,Xia Zhao,Baorong Hou
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摘要

Nacre-inspired coatings reinforced with amino-functionalized boron nitride nanosheets (NH 2 –BNNSs) were developed in this work. A hierarchical “brick and mortar” structure, where NH 2 –BNNSs act as “bricks” and epoxy resin act as “mortar”, was developed attributed to electrostatic repulsion between NH 2 –BNNSs modified by sodium carboxymethyl cellulose. In nacre-inspired coatings, penetration path of corrosive species must travel to reach metal surface was extended significantly, leading to hindered metal corrosion. Electrochemical impedance spectroscopy demonstrated | Z | f =0.01 Hz of aluminum alloy (AA5052) covered by nacre-inspired coating (NC-20) was 4 orders of magnitude higher than that of AA5052 covered by pure epoxy coating after 84 days of exposure in NaCl solution.

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