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Vanadium-catalyzed enantioselective oxidation of allyl sulfides

Journal 2011 · IF 2.484 · 发表于 2011 年 6 月 12 日
作者: Qingle Zeng,Yuxing Gao,Junyu Dong,Wen Weng,Yufen Zhao
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摘要

The enantioselective oxidation of allyl sulfides with a vanadyl complex of 3,5-diiodosalicylidene tert -leucinol as a catalyst and aqueous hydrogen peroxide as an oxidant afforded chiral allyl sulfoxides with high enantioselectivities of up to 97.3% ee and moderate yields.