Metal-organic frameworks-derived CoP anchored on MXene toward an efficient bifunctional electrode with enhanced lithium storage

It is significant to exploit novel electrode materials because at present the severe capacity decline and slow ion kinetics limit the broad application of lithium-based batteries. Herein, we have prepared the metal–organic frameworks-derived CoP anchored on Ti 3 C 2 MXene (MOFs-CoP@MXene) and fully explored its synergy as an efficient bifunctional electrode for enhanced lithium storage for the first time. It is gratifying that the prepared MOFs-CoP@MXene provides a high capacity of 706.5 mAh g −1 after 200 cycles at 0.2 A g −1 , as the anode for lithium-ion batteries (LIBs). It can provide 585.8 mAh g −1 after 1000 cycles with 0.5 A g −1 . The MOFs-CoP@MXene anode has robust lithium-ion storage capacity, indicating that it can increase the charge transfer rate and improve Li + diffusion kinetics with enhanced electrochemical activity. As lithium-sulfur batteries (LSBs) cathode, MOFs-CoP@MXene/S shows 796.9 mAh g −1 after 300 cycles at 0.2C. MOFs-derived CoP coupling with MXene exhibits enhanced capture capacity of sulfur, facilitating the conversion of polysulfides. The results show that the MOFs-CoP@MXene composite prepared for the first time are feasible as both the anode of LIBs and the cathode of LSBs.