Ni-MOF coating MoS2 structures by hydrothermal intercalation as high-performance electrodes for asymmetric supercapacitors

Two-dimensional metal-organic frameworks and nanoflowers of the MoS 2 form a composite structure as an electrode material for high-performance supercapacitor application. MoS 2 expands in the accordion-type Ni-MOF layers, and -S- joins the two materials to form a Ni-MOF coating MoS 2 composite structure. The composite material MoS 2 @Ni-MOF combines the structural characteristics of the Ni-MOF and MoS 2 , and effectively improves the electrochemical performance. The basic skeleton structure of the MoS 2 @Ni-MOF material remains unchanged, showing a remarkable specific capacitance of 1590.24 F·g −1 at a current density of 1.0 A·g −1 and an excellent cycle stability (retention rate of 87.97% after 20,000 cycles at current of 5.0 A·g −1 ). Due to the special composite structure of MoS 2 @Ni-MOF, the as-assembled MoS 2 @Ni-MOF//AC assymmetric supercapacitor (ASC) device exhibits a maximum energy density of 72.93 Wh·kg −1 at a power density of 375 W·Kg −1 . These excellent electrochemical properties indicate that the MoS 2 @Ni-MOF has potential applications in energy storage devices.