Photo-Fenton Degradation of Ciprofloxacin by Novel Graphene Quantum Dots/α-FeOOH Nanocomposites for the Production of Safe Drinking Water from Surface Water

In the current work, novel graphene quantum dots (GQDs)-doped goethite (α-FeOOH) nanocomposites (GQDs/α-FeOOH) were prepared by following a feasible hydrolysis method and applied for ciprofloxacin (CIP) removal. Results showed that the CIP degradation efficiency was significant (93.73%, 0.0566 min−1) in the GQDs/α-FeOOH + H2O2+ Vis system using much lower amounts of H2O2(0.50 mM), which is 3.9 times the α-FeOOH + H2O2+ Vis system. It was found that •OH,O2•−, and1O2were mainly responsible for CIP degradation in the GQDs/α-FeOOH photo-Fenton system. GQDs/α-FeOOH demonstrated broad-spectrum UV–vis-IR responsiveness in the degradation of ciprofloxacin as a function of the doping of GQDs. Additionally, GQDs/α-FeOOH showed outstanding durability (recyclability up to 3 cycles with a lower iron leaking amount, 0.020 mg L−1), a broad range of application pH, and a pretty acceptable catalytic efficacy in a variety of surface water matrices. Overall, GQDs/α-FeOOH have been shown to be an effective photocatalyst for the remediation of emerging contaminants via the workable exploitation of solar energy.Keywords:GQDs;goethite;emerging contaminants;photo-Fenton-like reaction;water pollution