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Ge nanoparticles embedded in spherical ordered mesoporous carbon as anode material for high performance lithium ion batteries

Journal 2018 · IF 5.116 · 发表于 2018 年 8 月 13 日
作者: Min Zhao,Dong-Lin Zhao,Xin-Yao Han,Hui-Xian Yang,Ya-Jing Duan,Xin-Min Tian
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摘要

Germanium-based anode materials suffer from huge volume expansion during the lithium ion insertion/extraction process, along with particle agglomeration, resulting in electrodes destruction and batteries failure. Ge nanoparticles embedded in spherical ordered mesoporous carbon (S-OMC/Ge) composite could effectively alleviate the defects in the cycle, which provided a novel material with stable cycle performance, high capacity and good conductivity. The S-OMC/Ge composite maintained reversible capacities of 996 mAh·g −1 after 160 cycles at a current density of 100 mA g −1 and 530 mAh·g −1 at a high rate of 1 A g −1 , attributed to the synergistic effect between the support of spherical OMC and the high capacity provided by dispersed Ge particles.