Efficient extraction of 68Ge from irradiated Ga–Ni alloy via a novel organic-solvent-free separation procedure

In this work, a gallium–nickel alloy target with a weight percentage ratio of 7:3 was successfully prepared on Cu substrate in a chloride system at room temperature. A novel organic-solvent-free separation procedure based on two columns for extracting 68 Ge from irradiated Ga–Ni alloy target with high radionuclidic purity (99.99 %) was developed. By this separation procedure, the recovery of 68 Ge is 95 ± 5 % and the yield of 68 Ge via the nuclear reaction nat Ga(p, x n) 68 Ge was measured to be 0.27 ± 0.02 MBq/μA h.