Co-Doping of Al3+ and Ti4+ and Electrochemical Properties of LiNiO2 Cathode Materials for Lithium-Ion Batteries

Graphical Co - doping modification of LiNiO 2 : The replacement of Ni atoms with Al 3+ and Ti 4+ ions respectively can improve the charge/discharge cycling performance of LiNiO 2 cathode materials, and their co-doping can more efficiently suppress the Ni 2+ /Li + cation mixing, irreversible phase transition of H2 and H3. Thus, the electrochemical performances exhibit significant synergistic effects. LiNiO 2 cathode material for lithium-ion batteries has the advantages of high specific capacity, abundant resources, and low cost, but it suffers from difficulties in preparation, structural instability, and serious capacity decay. In this work, highly pure and layered structural LiNi 0.95 Al a Ti 0.05- a O 2 ( a =0, 0.025, 0.05) cathode materials were synthesized by a simply sol-gel method. The cation mixing of Ni 2+ and Li + , structural deterioration, irreversible conversion between H2 and H3 phases and unstable surface and CEI (Cathode-electrolyte interface) film can be effectively suppressed by co-doping with Al 3+ and Ti 4+ . A preferred LiNi 0.95 Al 0.025 Ti 0.025 O 2 sample provides a discharge specific capacity of 223 mAh g −1 at 0.1 C and 148.32 mAh g −1 at 5 C, a capacity retention of 72.7 % after 300 cycles at 1 C and a Li + diffusion coefficient of about 2.0×10 −9 cm 2 s −1 .