摘要
By increasing the activity and specific properties of the catalyst during oxygen reduction reactions (ORR), we hope to improve fuel cell performance and energy conversion efficiency. Using a single microwave step, the graphene oxide-decorated iron phthalate catalyst (FePcNs@GO) nanocomposites were synthesised. Some analytical techniques were used to validate the morphology and composition of Fe catalyst/graphene (FePcGO) and FePcNs@GO. In an oxygen-saturated environment, we conducted the ORR electrocatalytic studies on the prepared materials. The results demonstrate that when FePcNs@GO is combined with graphene oxide, it exhibits excellent electrochemical properties. In comparison to commercial FePc and 20% Pt/C, the overpotential is significantly lower. Under nitrogen-saturated conditions, the Fe 2+/3+ redox form potential in FePcNs@GO exhibits a more positive behaviour, which favours strong interactions between Fe 2+ and O 2 . In this work, we demonstrate that platinum-free catalysts have potential applications in ORR.
危险品化学品经营许可证(带存储)