Sandwich-structured Ti3C2Tx-MXene/reduced-graphene-oxide composite membranes for high-performance electromagnetic interference and infrared shielding

The electromagnetic interference (EMI) shielding abilities of MXene-based conductive nanocomposites are promising for ensuring the steady operation of electronic equipment and protecting people from electromagnetic radiation. The development of comprehensive membranes that satisfy all the essential requirements of excellent EMI shielding and infrared (IR) stealth performance remains a significant issue, despite the high EMI shielding capabilities of MXene-based composite membranes . Here, we report a sandwich-structured Ti 3 C 2 T x -MXene/reduced-graphene-oxide (MrG) membrane with high conductivities and abundant interior blowholes for high-performance EMI shielding and IR stealth. Taking advantage of the continuously conductive routes and distinctive porous structures, an 18-μm-thickness MrG membrane shows a high EMI shielding efficiency (EMI SE) of 89.1 dB and a satisfactory absolute EMI SE ( S S E /t) of up to 55282.8 d B ⋅ c m 2 ⋅ g − 1 , which is the best result for MXene-based nanocomposites with similar thickness. Moreover, the MrG membrane also exhibits superior thermal camouflage ability for objects in low-temperature circumstances (like winter) and high-temperature cases (like summer), demonstrating the great promise as high-performance EMI shielding membranes for IR stealth, security protection, and counter-surveillance.