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Liquid–Liquid Equilibrium for Ternary Systems of Water + 2,2,3,3-Tetrafluoro-1-propanol + Anisole/1-Octanol at 298.2, 308.2, and 318.2 K

Journal 2018 · IF 2.196 · 发表于 2018 年 8 月 3 日
作者: Bing Jia,Liping Wang,Mengmeng Yan,Hai Liu,Yingmin Yu,Qingsong Li
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摘要

Liquid–liquid equilibrium (LLE) data for ternary systems of water + 2,2,3,3-tetrafluoro-1-propanol + anisole/1-octanol were determined at temperatures of 298.2, 308.2, and 318.2 K under 101.3 kPa. The distribution coefficients and separation factors were calculated from experimental LLE data, which indicated that anisole/1-octanol extracted 2,2,3,3-tetrafluoro-1-propanol from aqueous solution with high efficiency. The consistency of the experimental LLE data was assessed by the Othmer–Tobias and Hand equations. Meanwhile, the NRTL and UNIQUAC models were successfully applied to regress and correlate the experimental data, presenting the root-mean-square deviations (RMSD) less than 1.0%. The relevant binary interaction parameters of these two models were also regressed.