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Synthesis of microfibrous-structured SS-fiber@beta composite by a seed-assisted dry-gel conversion method

Journal 2017 · IF 3.615 · 发表于 2017 年 5 月 8 日
作者: Jia Ding,Pengjing Chen,Jian Zhu,Guofeng Zhao,Ye Liu,Yong Lu
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摘要

Microfibrous-structured SS-fiber@beta composites are synthesized by coupling dip-coating method with a seed-assisted dry-gel conversion method. The beta crystals in zeolite shell are formed by growth on the surface of pre-added beta seeds and TEAOH-induced nucleus. One interesting point is that this approach is working highly effectively and efficiently even at high dry gel SiO 2 /Al 2 O 3 ratio of 200 (corresponding to 207 in the beta zeolite shell). Such SS-fiber@beta composites show great potentials for the heat/mass transfer limited reactions due to their hierarchical porosity , small crystals, controllable acidity as well as our distinctive microfibrous-structured design.