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Superhydrophobic coatings based on thermally and chemically stable fluorinated poly(aryl ether)/SiO2/carbon nanotube

Journal 2021 · IF 3.089 · 36(8): 1705-1717 · 发表于 2021 年 5 月 10 日
作者: Yang Shuo,Li Zhiwen,Zhang Wenmeng,Lin Meijin,Chen Dongyang
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摘要

The thermal and chemical stabilities are two key factors limiting the commercial application of superhydrophobic coatings. Herein, a thermally and chemically stable fluorinated poly(aryl ether) (FPAE) was used for the first time to construct superhydrophobic coatings by a facile solution spraying process. Distinct nanosheet structures were formed for the FPAE, which after the incorporation of SiO 2 and carbon nanotube (CNT) turned into a hydrangea -like structure with high roughness and low surface energy. As a result, superhydrophobic coatings were obtained with the water contact angle (WCA) reaching about 170° and the rolling off angle (RA) reaching less than 1°. The superhydrophobicity was maintained after a variety of rigorous tests, including high-temperature baking, acidic and alkaline solution immersions, ultrasonic treatments, friction evaluations, etc. The self-cleaning, anti-corrosion, and oil–water separation capabilities of the FPAE/SiO 2 /CNT coating were successfully demonstrated. Therefore, the FPAE is a promising resin for the preparation of low-cost and high-performance superhydrophobic coatings. Graphic abstract