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Influence of Ag Nanoparticles on the Photoluminescence of WO3-WS2 Flake

Journal 2023 · IF 2.1 · 53(2): 899-906 · 发表于 2023 年 12 月 6 日
作者: Wang Caiyun,Zhou Yanhong,Liu Zhimin
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摘要

A composite of WO 3 and WS 2 has a wider wavelength range of light adsorption and light emission than WS 2 . A noble metal nanostructure can be utilized to adjust the photoluminescence (PL) of luminescent materials. In this study, WO 3 -WS 2 flakes were synthesized. A straightforward bath method has been employed to synthesize Ag nanoparticles (NPs). The average size of Ag NPs is approximately 60 nm. The Fourier transform infrared (FT-IR) peak of WO 3 -WS 2 flake at 495 cm −1 is from an alkane S–S bond stretching vibration. The PL intensity of WO 3 -WS 2 was attenuated subsequent to its integration with Ag NPs. The PL quantum yield of the WO 3 -WS 2 /Ag composite can reach 0.11%. This occurrence can be explained by the pronounced resonance absorption and diminished light extraction induced by the Ag NPs. This decreased light emission of the Ag NPs incorporated with WO 3 -WS 2 may be employed in some situations needing extinction, such as photography and projection. Graphical Abstract