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Synthesis, characterization, and visible photocatalytic performance of Zn2GeO4 nanobelts modified by CdS quantum dots

Journal 2012 · IF 3.461 · 发表于 2012 年 12 月 19 日
作者: Xiao-Liang Mao,Dong-Xing Xu,Ming-Lai Fu,Baoling Yuan,Jian-Wen Shi,Hao-Jie Cui
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摘要

Zn 2 GeO 4 nanobelts modified by CdS quantum dots (Zn 2 GeO 4 /CdS) were prepared successfully by chemical bath deposition. The novel photocatalyst was characterized by X-ray diffraction, scanning electron microscopy, X-ray photoelectron spectroscopy and UV–Vis diffuse reflectance spectroscopy. It was found that Zn 2 GeO 4 /CdS consisted of uniform rhombohedral phase Zn 2 GeO 4 nanobelts with highly dispersed cubic phase CdS quantum dots, and the Zn 2 GeO 4 /CdS exhibited strong visible light absorption at about 510   nm. The photocatalytic activities of the catalysts were evaluated by the discoloration of Rhodamine B under visible light illumination and were compared with that of pure Zn 2 GeO 4 nanobelts. The results suggested that the composite photocatalyst had much higher photocatalytic activities than pure Zn 2 GeO 4 nanobelts under irradiation of visible light. Meanwhile, no obvious deactivation of Zn 2 GeO 4 /CdS was observed after the three recycles experiments in photodegradation of RhB. The possible mechanism of visible light photocatalytic degradation is also proposed.