Supramolecular imprinted electrochemical sensor for the neonicotinoid insecticide imidacloprid based on double amplification by Pt-In catalytic nanoparticles and a Bromophenol blue doped molecularly imprinted film

The authors describe an electrochemical sensor for the neonicotinoid insecticide imidacloprid (IMI) based on Pt-In catalytic nanocomposite film and Bromophenol blue amplification. The Pt-In nanocomposite film was deposited on the surface of a modified glassy carbon electrode. The composite molecularly imprinted polymer (MIP) was prepared by electro-polymerization using bromophenol blue doped o -aminophenol as functional monomer and 4-tert-butylcalix[6]arene-IMI supramolecular inclusion complex as template molecule. The experimental results showed that the current intensity of IMI was clearly amplified in the potential range from −0.3 to −1.8 V, because of the double amplification, based on the Pt-In film and Bromophenol blue catalysis. Moreover, the double recognition ability of the sensor, which relied on the MIP and the vacuum structure of 4-tert-butylcalix[6]arene, effectively increased the specific recognition performance. The feasibility of its practical applications has been demonstrated by the analysis of vegetable samples. A supramolecular imprinted electrochemical sensor for imidacloprid determination was prepared based on Pt-In nanocomposite film and bromophenol blue amplification. Because of the advantages of the specific recognition sites in MIPs and supramolecular chemistry, the sensor showed good selectivity for imidacloprid.