One-pot synthesis of N-doped carbon intercalated molybdenum disulfide nanohybrid for enhanced adsorption of tetracycline from aqueous solutions

Nitrogen-doped carbon intercalated molybdenum disulfide nanohybrid (NC-MoS 2 ) with well-interconnected nanosheets was successfully fabricated using a one-pot hydrothermal method and applied as a novel adsorbent to remove tetracycline (TC) from aqueous solutions. Series material characterizations indicated that the intercalation of nitrogen-doped carbon into MoS 2 nanosheets could produce widened interlayer spacing, enlarge the specific surface area and create more extensive functional groups. The adsorption kinetics and isotherms investigations revealed that the pseudo-second-order model and Langmuir isotherm model could fit well the TC adsorption behavior of NC-MoS 2 . Particularly, NC-MoS 2 possessed a high maximum adsorption capacity (1128.4 mg/g) that was approximately 2.8 times that of pristine MoS 2 (409.84 mg/g) at 308 K and pH = 6.0 ± 0.1. Furthermore, the relevant thermodynamic parameters indicated that the adsorption process was spontaneous and endothermic. The adsorption process was dependent on multiple interactions including hydrophobicity , π-π stacking interaction and hydrogen bond . These findings demonstrated that NC-MoS 2 had potential applications for treating TC-containing water and broadened the application of metal sulfides in the environmental field.