Surface Engineering of Carbon Fiber Paper toward Exceptionally High-Performance and Stable Electrochemical Nitrite Sensing

In this work, we introduce our recent finding that the carbon fiber paper (CFP) treated by simple air annealing (OCFP) could be used for exceptionally high-performance electrochemical nitrite sensing. The air-annealing process endows the pristine CFP with higher defective edge/plane sites, more oxygen-containing functional groups, higher roughness, and improved wettability. The electrochemical studies show that the OCFP exhibits excellent sensing performance for nitrite, with an ultralow determination limit of 0.1 μM and a detection limit of 0.07 μM, an ultrawide linear determination range of 0.1–3838.5 μM, a fast current response of 1 s, and a high sensitivity of 930.4 μA mM–1 cm–2. These performance values are comparable or even superior to those for most reported noble- or transition-metal-based advanced nitrite sensors. Besides, this electrode also presents satisfactory stability, reproducibility, and feasibility of nitrite sensing in food samples. As an ideal monolithic and metal-free catalyst with ultrahigh and stable detection performance, the OCFP has a high potential to be integrated into next-generation electrochemical sensing devices.