Microwave-based preparation and characterization of Fe-cored carbon nanocapsules with novel stability and super electromagnetic wave absorption performance

Microwave-metal discharge was proposed as a facile methodology to prepare unique Fe-cored carbon nanocapsules (Fe@CNCs) with high purity, novel stability and extraordinary electromagnetic wave (EMW) absorption performance . The effect of microwave power, irradiation time and cyclohexane/ferrocene ratio on the production of Fe@CNCs was examined and the properties of the nanocapsules, such as their Fe content , phase, yield, degree of graphitization and associated microstructures were investigated in detail. It was found that the prepared Fe@CNCs, which can easily be separated from the reaction system, displayed exceedingly high electromagnetic wave (EMW) absorption performance over the 2–18 GHz range. At the minimal reflection loss (RL) values over −10 dB, the EMW absorption bandwidth can reach up to 13.8 GHz with an absorber thickness of 1.5–5 mm. In addition, novel thermo-oxidative stability and super anti-corrosion property were also obtained for the Fe@CNCs as no signs of any corrosion or oxidative degradation loss were observed from the accelerated degradation tests in air and acid at temperatures up to 420 °C. The exceedingly high EMW absorption performance coupled with the superior anti-degradation and anti-corrosion properties of the prepared nanocomposite microcapsules highlights the novel capability of microwave-metal discharge in synthesizing advanced metal-cored nanocarbon microcapsules with promising application potentials in diverse fields, such as but not limited to microwave absorption, EM shielding and advanced separations etc.