Accelerating water dissociation kinetic in Co9S8 electrocatalyst by mn/N Co-doping toward efficient alkaline hydrogen evolution

Electrocatalytic hydrogen evolution under alkaline media holds great promising in hydrogen energy production. Transition-metal sulfides (TMSs) are attractive for electrocatalytic alkaline hydrogen evolution, yet their catalytic performance is unsatisfactory owing to the sluggish water dissociation kinetics. Herein, a Mn/N co-doping strategy is proposed to regulate the water dissociation kinetics of Co 9 S 8 nanowires array grown on nickel foam thus improve the activity of hydrogen evolution reaction (HER). The optimal Mn/N co-doping Co 9 S 8 (Mn–N–Co 9 S 8 ) catalyst achieves low overpotentials of 102 and 238 mV at 10 and 100 mA cm −2 in the 1 M KOH solution, respectively, remarkably higher than the single-doping Mn–Co 9 S 8 and N–Co 9 S 8 as well as superior to many reported Co 9 S 8 -based HER electrocatalysts . Density functional theory (DFT) calculation results confirm that the water dissociation barrier of the Mn–N–Co 9 S 8 is reduced significantly owing to the synergistic co-doping of Mn and N, which accounts for the enhanced alkaline HER performance. This study offers an effective strategy to enhance the alkaline HER activity of TMSs by accelerating water dissociation kinetic via the cation and anion co-doping strategy.