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Growth of Eu(OH)3 large single crystals by solid KOH assisted hydrothermal method and luminescent and magnetic properties

Journal 2016 · IF 0.908 · 51(9): 508-512 · 发表于 2016 年 7 月 25 日
作者: Hai Wu,Youjin Zhang,Maozhong Zhou,Chengpeng Yao,Xianjin Ge
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摘要

Large single crystals of lanthanide hydroxides [Ln(OH) 3 (Ln = La, Pr, Nd, Sm, Eu and Tb)] up to several millimeters have been grown by using solid KOH assisted hydrothermal method. Eu(OH) 3 samples, as a representative of the Ln(OH) 3 crystals, were characterized by X-ray diffraction (XRD), 4-circle single-crystal diffraction, Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS). FESEM image shows hexagonal prism morphology for the Eu(OH) 3 large crystals. Research on the photoluminescence and magnetic properties of Eu(OH) 3 species was conducted.