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Energy level regulation to optimize hydrogen sensing performance of porous bimetallic gallium-indium oxide with ultrathin pore walls

Journal 2021 · IF 7.46 · 发表于 2021 年 10 月 2 日
作者: Qihua Liang,Yunjia Guo,Hui Chen,MeiHong Fan,Ni Bai,Xiaoxin Zou,Guo-Dong Li
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摘要

Although hydrogen sensors with high-response have been extensively studied and developed, it is still a great challenge to achieve ultra-fast response and recovery, high sensitivity and excellent selectivity towards hydrogen (H 2 ) for a gas sensor. Herein, porous Ga-In bimetallic oxide with atomically thin pore wall was synthesized by electrospinning and followed calcination . The sensor based on this sensing material (Ga 1.2 In 0.8 O 3 ) showed ultra-short response and recovery time (≈1 s and 3 s), high response (R a /R g ≈15–500 ppm H 2 ), good reproducibility, remarkable stability, low detection limit (2 ppm) and excellent selectivity (without cross-response to carbon monoxide). The enhanced hydrogen gas sensing performance of this material can be attributed to its novel atomically thin wall, optimal Fermi level and abundant chemisorbed oxygen.