One-pot synthesis of SnO2/reduced graphene oxide nanocomposite in ionic liquid-based solution and its application for lithium ion batteries

A facile and low-temperature method is developed for SnO 2 /graphene composite which involves an ultrasonic-assistant oxidation–reduction reaction between Sn 2+ and graphene oxide in a choline chloride–ethylene glycol based ionic liquid under ambient conditions. The reaction solution is non-corrosive and environmental-friendly. Moreover, the proposed technique does not require complicated infrastructures and heat treatment. The SnO 2 /graphene composite consists of about 4   nm sized SnO 2 nanoparticles with cassiterite structure mono-dispersed on the surface of reduced graphene oxide. As anode for lithium-ion batteries, the SnO 2 /graphene composite shows a satisfying cycling stability (535   mAh   g −1 after 50 cycles @100   mA   g −1 ), which is significantly prior to the bare 4   nm sized SnO 2 nanocrsytals. The graphene sheets in the hybrid nanostructure could provide a segmentation effect to alleviate the volume expansion of the SnO 2 and restrain the small and active Sn-based particles aggregating into larger and inactive clusters during cycling.