Preparation and characterization of novel crown ether functionalized ionic liquid-based solid-phase microextraction coatings by sol–gel technology

A novel crown ether functionalized ionic liquid (IL), 1-allyl-3-(6′-oxo-benzo-15-crown-5 hexyl) imidazolium hexafluorophosphate was synthesized and used as selective stationary phase to prepare task-specific IL-based solid phase microextraction (SPME) fibers by sol–gel method and free radical cross-linking technology. The underlying mechanism of the sol–gel reaction was proposed and the successful chemical bonding of the crown ether functionalized IL to the formed hybrid organic–inorganic copolymer coating was confirmed by FT-IR spectroscopy. The performance of this in situ created crown ether functionalized IL-based SPME fibers, was investigated in detail. The coating has porous surface structure, stable performance in high temperature (to 340   °C) and in different solutions (water, organic solvent, acid and alkali), and good coating preparation reproducibility. In contrast to the sol–gel derived 1-allyl-3-methyl imidazolium hexafluorophosphate-based coating prepared in our previous work with the identical procedure, the extraction performance of this newly developed sol–gel crown ether functionalized IL-based coating was superior for alcohols, phthalate esters , phenolic environmental estrogens, fatty acids and aromatic amines due to the introduction of benzo-15-crown-5 functional group in IL structure. Moreover, it was shown to provide higher or comparable extraction efficiencies for most analytes studied than did the commercial PDMS , PDMS/DVB and PA fibers.