The copper size effect of CuZn/CeO2 catalyst in CO2 hydrogenation to methanol

The escalating emission of CO 2 has caused a significant environmental impact. Hydrogenation of CO 2 to methanol stands as the primary objective in the liquid sunlight vision, aiming to mitigate CO 2 emissions. CuZn-based transition metal catalysts, known for their cost-effectiveness, demonstrate commendable catalytic performance at moderate temperatures and pressures, showcasing considerable potential in industrial applications. Consequently, a series of catalysts, composed of CuZn-based species supported on CeO 2 with strategically introduced appropriate oxygen vacancies, were meticulously prepared. It worth to noting that the size of Cu was precisely tuned, along with the enhanced ability to the adsorption and activation of CO 2 and H 2 . As a result, the optimal CuZn/CeO 2 catalyst exhibits high methanol formation rate, recording at 433.4 g MeOH kg cat −1 h −1 with selectivity of 68.5% at 260 °C and 3 MPa. Simultaneously, the reaction path and the evolution of intermediates in CO 2 hydrogenation was thoroughly delineated.