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Flexible N-doped TiO2/C nanofibrous film-based photocatalytic fabric with high photocatalytic activity and excellent reusability

Journal 2022 · IF 2.983 · 128(2): 1-8 · 发表于 2022 年 1 月 21 日
作者: Song Lixin,Qi Xueyang,Jing Wanru,Ke Huizhen,Chen Wei-Hsiang,Xiong Jie
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摘要

The flexible nitrogen (N) doped TiO 2 /C nanofibrous film (NTC f ) was fabricated by a combination of electrospinning and annealing treatment. The BET surface area of the NTC f increases, reaches largest value, and then decreases slightly with increasing of N. And the NTC f -20 has a maximum BET surface area of 175.60 m 2 ·g −1 . These are beneficial to the absorption of dye by the photocatalyst. At the same time, the N doping could increase the light absorption of TiO 2 and is favorable to the charges transfer of the carbon nanofibers, resulting in improving the photocatalytic activity of NTC f under visible light. As a result, all the NTC f showed excellent photocatalytic performance. Moreover, with the increase of N concentration, the photocatalytic activity of the NTC f increased, reaching the largest value before decreasing. And the highest photocatalytic degradation efficiency of Rhodamine B (RhB) was about 99.1% for 1 h by using NTC f -20. After that, the NTC f film was stuck on organza fabric to form a photocatalytic fabric by hot pressing. And the photocatalytic fabric with degradation efficiency of 98.5% was easily separated from the dye solution and possessed excellent reusability. It has huge potential application in pollutant disposal in flowing water.