Facilitated transport separation of CO2 and H2S by supported liquid membrane based on task-specific protic ionic liquids

Selective separation of CO 2 and H 2 S from CH 4 is of importance to the natural gas upgrading because of its corrosivity. As is well known, amine group can recognize reversibly CO 2 and H 2 S with a moderate interaction. With this in mind, this work prepared a series of amine-functionalized supported-protic-ionic-liquid membranes (SPILMs) for the selective separation of CO 2 and H 2 S from CH 4 . For comparison, aprotic ionic liquid membrane was also prepared for natural gas sweetening. The effect of temperature and transmembrane pressure difference on the permeability of single gas and ideal selectivity of CO 2 /CH 4 and H 2 S/CO 2 were studied. Facilitated transport mechanism was studied by NMR spectra. The permeability of CO 2 in primary amine functionalized [DMPDAH][Tf 2 N]-based membrane decreases with the increasing transmembrane pressure, indicating a typical feature of facilitated transport membrane. The permeability of CO 2 and the ideal selective of CO 2 /CH 4 are as high as 2000 barrers and 53.2 at 313.2 K in [DMPDAH][Tf 2 N] membrane, significantly higher than those in conventional ILs membrane. It is anticipated that these amine-functionalized SPILMs can provide alternative insight for the selective separation of CO 2 and H 2 S from CH 4 .