Carbon-coated monoclinic NbOPO4 with polyanionic framework for rechargeable aqueous lithium-ion batteries beyond 2 V

The choice of anode materials for high-voltage aqueous batteries beyond 1.5 V is still far from satisfactory, due to the narrow electrochemical stability window of aqueous electrolytes . With the inherent advantages of low working voltage and fast ionic diffusion, niobium phosphates with polyanionic framework groups built of NbO 6 octahedra and PO 4 tetrahedra are very promising anode materials for high-voltage aqueous batteries. Herein, carbon-coated NbOPO 4 (NPO/C) materials with monoclinic structure has been prepared by the solid-state reaction & chemical vapor deposition method. Between -1.34 V and 0.6 V vs. standard hydrogen electrode, it could deliver a specific capacity of 116 mAh/g with a high coulombic efficiency of 92.0% at a low current rate of 0.33C in aqueous electrolytes based on methylsulfonylmethane, LiClO 4 and H 2 O (DES). The diffusion-controlled process dominates the electrochemical reaction of NPO/C. Upon the reversible insertion/extraction of lithium ion into/from NPO/C, it maintains the monoclinic structure with a small lattice expansion, which is a characteristic of zero-strain effect. Finally, the full cell based on NPO/C anode, LiMn 2 O 4 cathode and DES electrolytes with a high specific energy 101.6 Wh/kg and a high voltage output beyond 2 V has been validated. It also shows excellent cycling performance with the capacity retention of 94.3% after 1000 times at 2C rate, which suggests that monoclinic β-NbOPO 4 can be used as a promising electrode material for aqueous lithium-ion batteries with high voltage output for energy storage in the future.