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Cu3Pt/Cu2O nanorod array prepared by a facile method for glucose detection

Journal 2020 · IF 6.182 · 发表于 2020 年 8 月 19 日
作者: Bingwang Yang,Ning Han,Liying Zhang,Shasha Yi,Zongtao Zhang,Yu Wang,Ying Zhou,Deliang Chen,Yanfeng Gao
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摘要

The combination of noble metal and transition metal oxide (TMO) can effectively expand their application in electrochemistry. However, rational design and convenient fabrication of the noble metal/TMO nanoarray is rarely reported. Here, Cu 3 Pt/Cu 2 O nanorod array was constructed on copper substrate by a convenient method and used as non-enzymatic glucose detector. In the nanorod, Moreover, the glycol ligand acted as a bridge for electron transfer from Cu 2 O at surface to Cu 3 Pt and the nanorod structure of Cu 3 Pt could serve as a highway for electron transfer, hence, when the Cu 3 Pt/Cu 2 O nanorod array was used as glucose detector, it delivered enhanced linear detection range (0.005–0.1 mM, 0.1–1.5 mM and 1.5–10 mM), high corresponding sensitivity (5082 μA mM −1 cm −2 , 3331 μA mM −1 cm −2 and 118 μA mM −1 cm −2 ), fast response time (<6 s), low detection limit (1.759 μM, S/N = 3) and high selectivity.