Efficient photodegradation of polystyrene microplastics integrated with hydrogen evolution: Uncovering degradation pathways

Photocatalytic microplastics (MPs) conversion into valuable products is a promising approach to alleviate MPs pollution in aquatic environments. Herein, we developed an amorphous alloy/photocatalyst composite (FeB/TiO 2 ) that can successfully convert polystyrene (PS) MPs to clean H 2 fuel and valuable organic compounds (92.3% particle size reduction of PS-MPs and 103.5 μmol H 2 production in 12 h). FeB effectively enhanced the light-absorption and carrier separation of TiO 2 , thereby promoting more reactive oxygen species generation (especially ‧OH) and combination of photoelectrons with protons. The main products (e.g., benzaldehyde, benzoic acid, etc.) were identified. Additionally, the dominant PS-MPs photoconversion pathway was elucidated based on density functional theory calculations, by which the significant role of ‧OH was demonstrated in combination with radical quenching data. This study provides a prospective approach to mitigate MPs pollution in aquatic environments and reveals the synergistic mechanism governing the photocatalytic conversion of MPs and generation of H 2 fuel.