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Rh(III)-Catalyzed Csp2−Csp3 Bond Cleavage/Carbonylethylation of α-Indolyl Alcohols

Journal 2021 · IF 5.837 · 363(6): 1672-1684 · 发表于 2021 年 1 月 22 日
作者: Zhipeng Liu,Xinwei Hu,Can Yang,Haisheng Xie,Huanfeng Jiang,Wei Zeng
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摘要

Graphical A Rh(III)-catalyzed C sp 2 −C sp 3 bond cleavage/carbonylethylation of α-indolyl alcohols with allylic alcohols has been reported. This transformation involved a cascade C−C bond cleavage/C−C bond formation, and provides a novel approach to assemble 2-carbonylethylindole skeletons.