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Preparation and fluorescence property of porous Ti/perovskite composites

Journal 2024 · IF 5.1 · 发表于 2024 年 7 月 2 日
作者: Tianqing Sheng,Shuqin Zhang,Xuguang Wei,Xinran Lv,Zhigang Yang
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摘要

The porous Ti/perovskite composites were prepared successfully by ultrasound-assisted infiltration method. The Cs–Pb–Br perovskite materials were prepared on a larger scale by the mechanical ball-milling using the CsBr and PbBr 2 as the precursors. The Cs–Pb–Br perovskites had high PL intensity and excellent stability, meanwhile, the complex phase transformation between CsPbBr 3 and Cs 4 PbBr 6 occurred during the ball-milling process. The green fluorescence emission of composites might be attributed to CsPbBr 3 embedded within Cs 4 PbBr 6 perovskite. By the space occupying method, the porous Ti materials were prepared by using the acicular urea as the pore forming. The optimal young's modulus (1.0851 GPa) and porosity (38.27 %) were obtained. Finally, the prepared Ti/perovskite composites had outstanding fluorescence property and high stability, showing the wide application prospect in the fields of the bioflourescence imaging and nondestructive testing fields.