Bifunctional ratiometric fluorescent membrane containing pyrene-based probe for visual monitoring and efficient removal of Al3+

A bifunctional fluorescent pyrene-based probe, PYR , was designed by incorporating pyridine and phenolic hydroxyl moieties into pyrene fluorophore, which exhibited ratiometric fluorescent response toward Al 3+ . PYR underwent unique monomer-excimer conversion in ratiometric manner through the formation of a 2:1 coordination complex and accomplished with fluorescent color variation from green to blue. PYR displayed excellent selectivity , high sensitivity (LOD = 0.33 μM), rapid response (<45 s), and good cytocompatibility to Al 3+ . Notably, a fluorescent cellulose membrane decorated with PYR was successfully developed and applied for accurately quantify of Al 3+ in diverse actual samples, and high-efficiency removal (∼96%) of Al 3+ from water systems, with sustainable recycling performance up to 10 times. Bifunctional membranes also played an important role in reducing the LOD of Al 3+ to 16 nM through the preconcentration process. Therefore, this study is crucial to the development of environmentally sustainable strategy for monitoring and removing pollution.