Room temperature synthesis of Mn-doped Cs3Pb6.48Cl16 perovskite nanocrystals with pure dopant emission and temperature-dependent photoluminescence

In recent years, halide perovskites have attracted great attention as a type of well-known material, especially inorganic perovskites like CsPbX3 (X = Cl, Br, and I). Herein, we introduce a new family of doped nanocrystals offering unique insights into the synthetic chemistry of doped perovskites. Mn-Doped Cs3Pb6.48Cl16 nanocrystals with pure dopant emission were prepared at room temperature with a low Mn/Pb feed ratio (>1.4). The band edge luminescence of Mn:Cs3Pb6.48Cl16 was almost completely inhibited, and the photoluminescence quantum yields (PL QYs) of Mn ions could reach up to 25%. Furthermore, the temperature-dependent PL spectra and temperature-dependent lifetime of the new family of doped nanocrystals indicated that the inflection point affects both the PL intensity and the PL lifetime of Mn2+ ions with increasing the temperature, which is related to the Mn/Pb ratio.