摘要
A novel difunctionalization of unactivated alkenes has been reported via visible light-promoted three-component carboazidation using TMSN 3 and acrylonitrile as partners without any stoichiometric oxidants. This protocol is operationally simple for straightforward access to azido derivatives with good functional group tolerance from readily available starting materials. A facile azido radical-catalyzed [3 + 2] cycloaddition reaction of vinylcyclopropane with acrylonitrile was also observed to deliver a multi-substituted cyclopentane.
危险品化学品经营许可证（带存储）