Structure, Morphology, and Magnetic Properties of M-type Nb-doped Ferrite Prepared via Solid-state Sintering

BaFe 12− x Nb x O 19 ( x  = 0.00, 0.04, 0.08, 0.12, 0.16, and 0.20) with a nominal composition for M-type hexagonal barium ferrite was prepared using solid-state sintering methods. The microstructure and magnetic properties of hexaferrite were characterized using X-ray diffraction (XRD), Fourier-transform infrared (FTIR) spectroscopy, field-emission scanning electron microscopy (FESEM), and vibrating-sample magnetometry (VSM). XRD results revealed that the crystal structure of barium ferrite remained intact after Nb doping, maintaining a single barium ferrite phase. FESEM confirmed the hexagonal crystal structure of the sample. Energy-dispersive X-ray spectroscopy showed increased Nb content and decreased Fe content without the formation of other elements. FTIR revealed bands at 598 and 445 cm −1 corresponding to tetrahedral and octahedral clusters, respectively. The VSM test showed that the saturation magnetization ( M s ), residual magnetization ( M r ), and coercivity ( H c ) initially increased and then decreased with increasing Nb doping, reaching maximum values of 92.297 emu/g, 44.256 emu/g, and 3367.53 Oe, respectively, at x = 0.08.